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We use A or AN with singular nouns.
A is used when a noun starts with a consonant sound;
e.g. a dog, a book, etc.
AN is used when a noun starts with a vowel sound;
e.g. an apple, an hour, etc.
We use SOME with countable nouns (only with their plural) and with uncountable nouns.
SOME is used in:
* positive sentences;
e.g. I have got some time.
* questions, expressing requests and offers;
e.g. Would you like some tea?
Can I have some biscuits?